2,4-Diiodo-6-[(propylimino)methyl]phenol

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2,4-Diiodo-6-[(propyl­imino)­meth­yl]phenol

The title compound, C(10)H(11)I(2)NO, was prepared by the reaction of 3,5-diiodo-salicyl-aldehyde with propyl-amine in ethanol. The mol-ecule adopts an E conformation with respect to the C=N bond and the aromatic ring. The aromatic ring and the imino unit are close to being coplanar, with a dihedral angle of 2.6 (3)° between their planes. This planarity is assisted by the formation of an intra-...

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2,4-Diiodo-6-{[4-(morpholin-4-yl)phenyl]iminomethyl}phenol

In the title compound, C(17)H(16)I(2)N(2)O(2), the two aromatic rings are almost coplanar [dihedral angle 2.57 (15)°]. The morpholine ring adopts a chair conformation. The mol-ecular structure is stabilized by an O-H⋯N hydrogen bond and the crystal packing exhibits weak inter-molecular C-H⋯O and π-π [centroid-to-centroid distances 3.663 (3)-4.073 (3) Å] inter-actions.

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1,2-Diiodo-4,5-dimethyl­benzene

The structure of the title compound, C(8)H(8)I(2), conforms closely to the mm2 symmetry expected for the free mol-ecule and is the first reported structure of a diiodo-dimethyl-benzene. Repulsion by neighboring I atoms and the neighboring methyl groups opposite to them results in a slight elongation of the mol-ecule along the approximate twofold rotation axis that bis-ects the ring between the ...

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3,6-Diiodo-9H-carbazole

In the title compound, C(12)H(7)I(2)N, the tricyclic aromatic ring system is essentially planar, with an r.m.s. deviation of 0.0272 Å. The two I atoms are marginally out of plane, with the C-I bonds angled at 3.9 (2) and 1.1 (2)° with respect to the planes of their respective benzene rings, above and below the plane of the carbazole ring system. No classical hydrogen bonds are observed in the c...

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2,4-Diiodo-3-nitro­anisole

IN THE TITLE COMPOUND (SYSTEMATIC NAME 1,3-diiodo-4-meth-oxy-2-nitro-benzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π-π stacking occurs between inversion-related rings [centroid-centroid separation = 3.865 (3) Å and slippa...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812005727